There is only one TRV in the living room because the other valves are not thermostatic. I would need to replace those to achieve what you describe. But then I think that’s not the way to go because it could damage the pump from what I hear.
The boiler is a Remeha Tzerra Ace which supports Opentherm with modulation. It’s also wired on the opentherm contacts and the T6 supports it.
English is not my first language and although I can kinda get my point across, technical jargon is a bit of a blind spot. So just to clarify: I have a little vat of say 10 liters connected to the heating pipes. It’s next to the boiler. It contains a rubber membrane in the middle to expand if pressure builds. Is this the type of buffer you’re referring to?